With a Primary Password, your private key is encrypted in your *Thunderbird* profile and is only unlocked while *Thunderbird* is running.If your *Thunderbird* profile is stored in your Persistent Storage, then your private key is encrypted twice: once by *Thunderbird* in your profile and a second time by the encryption of the Persistent Storage.
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Click the **Select File to Import…** button and choose the private key that your exported from *Kleopatra*utility.