Immediately press-and-hold the <span class="keycap">Option</span> key (<span class="keycap">⌥</span> or <span class="keycap">Alt</span> key) when the startup sound is played.
[[!img install/inc/screenshots/grub.png class="screenshot" alt="Black screen ('GNU GRUB') with Tails logo and 3 options: 'Tails' and 'Tails (Troubleshooting Mode)' and 'Tails (External Hard Disk)'."]]